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Which is stronger HF or hi?

Ava Wilson | 2023-06-08 09:59:49 | page views:1723
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Oliver Lee

Works at the International Air Transport Association, Lives in Montreal, Canada.
As a chemical expert with a strong background in chemistry, I can provide a detailed analysis of the strength of hydrohalic acids, specifically focusing on the comparison between hydrofluoric acid (HF) and hydroiodic acid (HI).

Hydrohalic acids are a group of acids derived from the halogens, which include fluorine (F), chlorine (Cl), bromine (Br), and iodine (I). These acids are characterized by their ability to donate a proton (H+) and are considered to be strong acids, meaning they ionize completely in water to produce hydronium ions (H3O+).

When comparing the strength of HF and HI, it's important to consider several factors, including the electronegativity, atomic size, and bond strength of the halogen atoms.

Electronegativity: Electronegativity is a measure of an atom's ability to attract electrons. Fluorine is the most electronegative element, followed by chlorine, bromine, and then iodine. This high electronegativity of fluorine in HF leads to a strong polar bond, which makes it difficult for HF to donate a proton. On the other hand, iodine in HI is less electronegative, which means it holds onto its electrons less tightly, making it easier for HI to donate a proton.

Atomic Size: The size of the halogen atom also plays a role in the strength of the acid. Iodine, being the largest halogen, has a larger atomic radius. This larger size allows the iodine atom to stabilize the negative charge more effectively after donating a proton. Thus, the bond between the hydrogen and iodine in HI is weaker compared to the bond in HF, making HI a stronger acid.

Bond Strength: The strength of the H-X bond (where X is the halogen) is another factor. A stronger bond is harder to break, which means the acid is less likely to donate a proton. The H-F bond in HF is stronger than the H-I bond in HI due to the high electronegativity and smaller size of fluorine. This results in HF being a weaker acid compared to HI.

Acidity Trends: The acidity of the hydrohalic acids follows a trend based on the properties mentioned above. HI is the strongest acid, followed by HBr, HCl, and then HF. This trend is due to the decreasing electronegativity and increasing atomic size as you move down the halogen group.

In conclusion, hydroiodic acid (HI) is stronger than hydrofluoric acid (HF) due to its lower electronegativity, larger atomic size, and weaker H-I bond, which allows it to more readily donate a proton and ionize in water.


2024-05-26 01:47:22

Aiden Taylor

Works at Uber, Lives in San Francisco, CA
Iodine is so much bigger than fluorine that the charge is more stable on this larger atom. Thus, the trends for acidity of the hydrohalic acids are as follows: HI is strongest, followed by HBr, HCl, and finally HF.
2023-06-14 09:59:49

Benjamin Evans

QuesHub.com delivers expert answers and knowledge to you.
Iodine is so much bigger than fluorine that the charge is more stable on this larger atom. Thus, the trends for acidity of the hydrohalic acids are as follows: HI is strongest, followed by HBr, HCl, and finally HF.
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