Why hydrogen has a low boiling point 2024?

Julian Lopez | 2023-06-08 09:59:35 | page views:1598
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Benjamin Edwards

Works at the World Health Organization, Lives in Geneva, Switzerland.
As a subject matter expert in the field of physical chemistry, I often find myself explaining the properties of elements and compounds. One such property is the boiling point, which is a measure of the temperature at which a substance changes from a liquid to a gas. Hydrogen, the lightest and most abundant element in the universe, has a notably low boiling point. Let's delve into the reasons behind this phenomenon.

Boiling point is influenced by the strength of the intermolecular forces present in a substance. In the case of hydrogen, the intermolecular forces at play are primarily van der Waals forces, which include London dispersion forces and, to a lesser extent, dipole-dipole interactions. These forces are relatively weak compared to other types of intermolecular forces such as hydrogen bonding or ionic bonding.

London Dispersion Forces: These are the weakest of the van der Waals forces and arise due to temporary dipoles created by the movement of electrons in the molecules. Since hydrogen is a small atom, the electron cloud is relatively compact, leading to weaker London dispersion forces compared to larger molecules with more extensive electron clouds.

Dipole-Dipole Interactions: Hydrogen can form dipole-dipole interactions when it is part of a polar molecule, such as hydrogen chloride (HCl). However, molecular hydrogen (H2) is nonpolar due to the symmetrical distribution of the electron cloud between the two hydrogen atoms, which means it does not have a permanent dipole moment. The absence of a permanent dipole in H2 results in the lack of significant dipole-dipole interactions.

The strength of intermolecular forces is directly related to the boiling point of a substance. Stronger forces require more energy to overcome, thus leading to a higher boiling point. Conversely, weaker forces require less energy to break, resulting in a lower boiling point. Since hydrogen experiences only weak intermolecular forces, it has a low boiling point of approximately -252.87 degrees Celsius.

Furthermore, the boiling point is also affected by the molecular weight of a substance. Hydrogen, with an atomic mass of approximately 1 gram per mole, is the lightest element. Lighter molecules generally have lower boiling points because they require less energy to increase their kinetic energy to the point where they can overcome the intermolecular forces and transition into the gas phase.

In summary, hydrogen's low boiling point can be attributed to the weak intermolecular forces, namely London dispersion forces, and its low molecular weight. The absence of strong intermolecular forces and the ease with which these weak forces can be overcome by thermal energy at relatively low temperatures are the primary reasons for hydrogen's low boiling point.


2024-06-11 07:10:00

Lucas Kim

Works at the International Development Association, Lives in Washington, D.C., USA.
Intermolecular forces. All of these substances have very strong covalent bonds between the atoms, but much weaker forces holding the molecules together. ... Because the weak intermolecular forces break down easily these substances have low melting and boiling points.
2023-06-16 09:59:35

Isabella Patel

QuesHub.com delivers expert answers and knowledge to you.
Intermolecular forces. All of these substances have very strong covalent bonds between the atoms, but much weaker forces holding the molecules together. ... Because the weak intermolecular forces break down easily these substances have low melting and boiling points.
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