Which metals are refined by electrolytic refining?

Charlotte Henderson | 2023-06-07 13:40:40 | page views:1164
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Zoe Mitchell

Studied at the University of Melbourne, Lives in Melbourne, Australia.
I'm a metallurgical engineer with a strong background in the field of metal refining. Electrolytic refining is a process that is used to purify metals by dissolving impure metal anodes and plating pure metal onto cathodes through the application of an electric current. This method is particularly effective for metals that are prone to contamination during other refining processes.

Copper is one of the most commonly refined metals using electrolysis. The process begins with an impure copper anode, which contains various impurities such as nickel, gold, and silver. This anode is immersed in an electrolyte solution, typically a sulfuric acid solution. A cathode, usually made of pure copper, is also immersed in the solution. When an electric current is passed through the solution, copper ions from the anode dissolve and migrate towards the cathode, where they are deposited as pure copper. The impurities, being less reactive, do not dissolve and are left behind in the anode.

Lead can also be refined through electrolysis. The process is similar to that of copper, with impure lead serving as the anode and pure lead as the cathode. The electrolyte used for lead refining is typically a solution of lead sulfate or nitrate. The impurities in lead, such as antimony and arsenic, do not dissolve in the electrolyte and are left behind, resulting in a purer form of lead.

Nickel refining through electrolysis involves an anode made of impure nickel and a cathode of pure nickel. The electrolyte used is a solution of nickel sulfate. The process effectively removes impurities such as iron, cobalt, and chromium, leaving behind a high-purity nickel deposit on the cathode.

Silver and Gold are precious metals that can be refined using electrolysis. These metals are often found together in ores and are refined in a similar manner. The anode is made from the impure metal, and the cathode is pure silver or gold. The electrolyte used is a solution of silver or gold salts. During electrolysis, the silver or gold ions migrate to the cathode and are deposited as pure metal, while other impurities remain in the anode.

Zinc refining through electrolysis is a bit different due to its reactivity. The process involves zinc oxide as the anode and pure zinc as the cathode. The electrolyte is a solution of zinc sulfate. When electricity is applied, zinc ions are reduced at the cathode to form pure zinc, while oxygen is evolved at the anode from the zinc oxide.

Copper, Nickel, and Cadmium are also refined using electrolysis. The process for these metals is similar to that of copper, with each metal having its specific electrolyte solution. The impurities are left behind in the anode, and pure metal is deposited on the cathode.

In summary, electrolytic refining is a highly effective method for purifying a variety of metals. It is particularly useful for metals that are prone to contamination during other refining processes, ensuring a high level of purity and quality in the final product.


2024-05-19 19:55:09

Sophia Nguyen

Studied at Harvard University, Lives in Cambridge, MA
Electro-refiningCopper: In the actual copper-refining operation, the impure alloy of copper, nickel, gold, etc., is cast in a thin, flat plate constituting the anode: the cathode is usually a sheet of pure electrolytic copper. ... Lead: ... Nickel: ... Silver and Gold: ... Precious Metals. ... Zinc: ... Copper, Nickel, Cadmium: ... Precious Metals.
2023-06-11 13:40:40

Zoe Gonzalez

QuesHub.com delivers expert answers and knowledge to you.
Electro-refiningCopper: In the actual copper-refining operation, the impure alloy of copper, nickel, gold, etc., is cast in a thin, flat plate constituting the anode: the cathode is usually a sheet of pure electrolytic copper. ... Lead: ... Nickel: ... Silver and Gold: ... Precious Metals. ... Zinc: ... Copper, Nickel, Cadmium: ... Precious Metals.
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